The degassing experiment three was drawing to a close. To recap 100 grams of dark roasted beans were put in one flask, 100 grams of the same beans but ground were put in the other flask. After 24 hours 294 mls of CO₂ were released from the ground coffee. Even after 3 days the ground coffee maxed out at 300 mls supporting the literature ⁽¹⁾ that ground coffee degasses in 12-24 hours depending on grind.

The whole beans were a different story. The 130 ml of day one grew to 290 mls in nine days. The literature said about 7 days for most degassing. I was getting ready to clean up the experiment when I had an idea. Just for “shits and giggles” why not grind the nine day old beans. They had stopped releasing CO₂ but was there any inside that grinding would release? Using the same grinder settings as previous experiments I ground the 100 grams and quickly returned to the flask and stoppered. I was surprised to see gas released with a similar curve to freshly roasted coffee.

In one day 112 mls of CO₂ were released. Like fresh roast beans almost all of the release was in the first 24 hours. While only 38% of what a fresh roast grind release, the total release was 406 mls versus 296 for fresh ground.

I have not found any literature on CO₂ degassing in older coffee. I am going to continue other degassing experiments to open up the parameters of cause/effect.

My color spectrometer has not arrived yet. Really looking forward to experimenting with it.

References:

1. Development of an apparatus for measuring the degassing behavior of coffee with the option to examine the influence of protective gases for aroma preservation : KOZIOROWSKI, Thomas; BAUMEISTER, Heinrich; JANSEN, Gerhard; BONGERS, Sandra; PROBAT-WERKE, Emmerich, Germany – Probat

Experiment three was a chance to apply all of the lessons learned in measuring CO₂ degassing of roasted coffee.

Lesson 1: A photo copy stand was used to support the graduated cylinders. Fill the cylinders with water and place upside down in the tank. Lower the photo rack then support the cylinders with square wooden rods, hold with several rubber bands then raise the attached cylinders with the camera holder adjuster.

Lesson 2: Using eyedroppers is very effective but you have to slightly point them downhill or the air will escape, just slower. The most effective dropper has a turn on the end pointing down. This made it easier to prevent gas escaping and water filling the line. The eye droppers were purchased at Walmart for $2 a pair. Keep the eyedroppers as close to the cylinder bottom without touching. Water pressure becomes a factor if you put them deep in the water.

Lesson 3: The critical timing is from grinding the coffee, place in the flask, weigh and stopper. By putting a funnel in the flask on the scale ground coffee could be scooped quickly and accurately.

Lesson 4: I wrote a trivial program to log the time vs the readings. This meant recording readings was just typing in the levels. The program tracked the time. For the time value I used a Unix Timestamp, the number of seconds since January 1 1970 00:00:00 GMT. So to calculate offset is simple subtraction from the first reading. The data was then copy/pasted into a spreadsheet for calculations and graphing.

Lesson 5: Track as many variables as possible. By using Artisan I could compare degas roast 2 to degas 3 roast.

Hours Ground ml CO2 Whole ml CO2 – 30 0 0.05 45 0 0.10 58 0 0.12 62 0 0.13 66 0 0.18 75 0 0.20 80 0 0.27 90 0 0.34 100 0 0.44 110 0 0.51 118 0 0.53 120 0 0.65 130 0 0.75 136 0 1.04 154 0 1.17 160 0 1.28 165 0 1.76 183 15 1.94 190 18 3.79 226 37 11.69 270 89 12.12 280 94 22.12 290 124 23.36 290 126 24.04 290 128 24.58 294 130 25.61 296 132 27.25 296 135 35.65 296 145 36.87 296 154 46.35 300 170 47.62 178 48.65 182 50.75 182 59.44 188 60.89 194 72.75 198 85.32 210 91.38 220 100.10 227 108.91 236 111.60 240 114.28 243 117.01 246 120.31 248 155.70 264 157.01 267 166.09 270

Hours vs ml CO2 Ground (Blue) vs Bean (Red)

Conclusion 1: Ground degassing is pretty well complete in this experiment at 12 hours. 280 ml of CO2 released at 12 hours while 300 by 48 hours. After day 3 the whole beans are still degassing but slowing down.

Next experiment is to repeat this setup but with a medium roast (430^o drop.) I also ordered a school grade color spectrometer and am investigating roast colour analysis.

Most Important Conclusion: Crawling into the raw science basics of roasting is really fun.

In this experiment, I roasted Costa Rica coffee to Full city. I dropped the roast at 450^oF. While I normally do not roast so dark, I knew from documentation this would result in more CO2 to be released.

I placed 100 grams of ground coffee in the the left flask, while 100 grams of whole beans were placed in the right flask. I loaded the ground coffee into the flask as quickly as possible, but the degassing speed surprised me. In one hour of capping the flask, 120 ml of CO2 was already released. This is much faster than whole bean degassing. In the previous whole bean experiment with a medium roast and twice the coffee it took 24 hours to release 120 ml.

Another change from the previous setup was to add eye droppers to the end of the tubes. This made it easier to see the bubbles form. Play the video to see how fast the ground coffee released CO₂.

Hours ml CO2 0 0 0.08 28 0.13 40 0.23 58 0.27 62 0.28 65 0.35 72 0.38 78 0.45 84 0.52 90 0.60 96 0.67 102 0.80 110 0.90 116 0.95 118 1.00 120 1.07 126 1.15 130 1.37 138 1.48 144 1.88 158 2.00 160 2.30 166 3.13 186 3.53 194 5.00 212 6.83 228 8.78 238 19.00 256 31.00 268

ml CO2 Released vs Hours

Roast profile from the Artisan tracking screen.

This shot image was captured with a Celestron digital microscope. The scale on the right is 1/16″. The beans were ground with a Macap MC4.

As I read more and more on how CO₂ is released from freshly roasted coffee I decided to try my own experiment. Basically the experiment is to measure the captured CO₂ as it is released. A basic experimental approach is to use an eudiometer.

My setup is not quite as elegant.

The purpose of this test is to try the setup. The flask is 500 ml with 211 grams (~7.4 oz.) of medium roast Costa Rica coffee. The beans were loaded 5 minutes after dump with a temperature of 94^oF. The graduated cylinder is 250ml and the tubing 1/4″ OD flexible copper. I am concerned that the inside diameter is large enough that air will escape up and water flow down. I will add a water dropper on the next version to keep water from going in and the air bubbling out. Also the tube should be shorter so that it is easier to get into the graduated cylinder.

Hours ml CO2 1.4 20 3.7 29 11.7 76 13.0 80 19.0 100 22.0 112 24.0 122 24.6 124 26.0 129 36.0 152 37.0 154 46.5 172 48.0 176 49.5 180 59.5 194 61.0 200 71.0 214 84.0 224 94.5 236 104.3 246 108.0 250

ml CO2 Released vs Hours

The papers I found said the degassing would continue on whole beans for 7 days. Now that the output reached 250 ml, the capacity of the graduated cylinder, I am going to end this experiment and set up one comparing whole bean and ground coffee. To avoid the 250ml capacity I will put in 100 grams of coffee.